Oneline:
mkdir -p {a..z}; for i in ./*; do export FILE=$(basename "$i"); export LTR=$(echo "${FILE:0:1}" | tr A-Z a-z); mv "$i" "$LTR/$FILE" ; done
Process:
mkdir -p {a..z}
for i in ./*
do
export FILE=$(basename "$i")
export LTR=$(echo "${FILE:0:1}" | tr A-Z a-z)
mv "$i" "$LTR/$FILE"
done